I believe you're talking about the leading edge, yes? If you haven't assembled the leading edge yet, don't worry about it. It's the last thing (or mostly the last thing you're going to do, when putting the leading edge on for good because you want to keep that off for access to be able to buck inside there. Just take those two ribs and put them away for a bit.
Wait until the leading edge is on (or if you want, cleco it all together and put it on then go ahead), then tap it into place, and just make marks on the web of the rib corresponding to the holes in the skin. Then take it out, extend the line around the corner onto the flange and...voila...there's your rivet spot. Flute between the lines.
Piece of advice.... use that hand seamer and get those flanges 90 degrees to the Web. And get the Band-Aids ready. (g)