Combining the information found in figures 27-2.12 and 27-2.14 in the current G3X installation manual (revision AQ), it looks like you want to connect the output from RS-232 port #6 (pins 22 and 42) on the GNS 480 to RS-232 port #2 (pins 24 and 50) on the GTX 33ES. The GNS 480 RS-232 output format should be configured to "ADS-B+" and the GTX 33ES RS-232 input should be configured to "Remote". If the software in your GNS 480 is very old you may need a software update to be able to configure the "ADS-B+" format.