No way, that I know of, to check for water. I suppose a mod could be done to the inboard end of the "tube", just before it plumbs into the main tank, to install a drain. I think that would be the lowest point in the ER tank. The pump and plumbing access panel in the bottom of the wing could be designed to allow access to the drain, for pre-flight fuel check.
I don't use my ER tanks too often and never have any water in my wing sumps on pre-flight.