I have an 8 kit but I'm at this same point getting ready to rivet the main ribs to the spars. I see no harm in dimpling the ribs after they've been primed and before I rivet them in place. Although it may actually be easier to dimple them with them hanging from the spars. Game time decision!
Edit: thinking about it, it will be sort of a pain to dimple the inboard most ribs, the group of 4 (in my kit) that are all right next to each other. So in that case, probably easier to dimple them now. That means in my case, final sizing the holes on the ribs before dimpling them. But now I'm over thinking all this which in my experience is the enemy of progresss, lol! What to do.... I'll have to read the instructions a bit to decide.
This is where the 10, 12 and 14 builders have an advantage as this kind of stuff is already thought out for you for the most part.