Soundproofing is relatively easy until we need to compromise something. The basics would be:
Mass: More heavier construction will reduce more. It's up to you how much you are willing to put weight on the firewall but as without anything it is very light/thin and therefore even smaller amount of material will reduce noise. For low frequency noise the mass is kind of a only way to reduce it in this case. The real sound proofing materials are relatively easy to use but expensive. However thumbrule would be: the most heavier by volume is the best for proofing and it may not be the most expensive and most advertised...
Distance/space: The further you get, the less you'll hear. In this case, your engine will be on the other side of the firewall and you on the other -- I hope. Therefore this can be considered as constant here.
Damping: Some things can get "resonating" and damping these down will reduce noise. Usually mass helps to reduce effect of this.
Use any search engine and you'll find a lot of information about the basics of soundproofing and different solutions to do it. But the basics were here already -- if we also consider that we ain't have space to make air gaps between the protective walls.
However since reducing noise remarkable by adding mass is relatively difficult in case of the airplane I would suggest another lighter option: active noise reduction (ANR) headsets or any other good headsets. ANR technique will reduce noise much more you can "ever" reduce by adding mass to the firewall and together these will get you to the new level of soundproofing.
Personally I would (I've) select ANR headsets, which has also passive attenuation due if electronics of ANR headsets will fail, I'll have my hearing after the flight. If you haven't ever tested ANR headsets do it now. They are more expensive than normal headsets, but will be defenitely worth of every penny. Headsets will last long and therefore calculated per flight hour the cost should be reasonable. Test before you judge them due high price!
I also found some articles about bigger plane sound proofing. I didn't read all through but there might be some tricks:
http://www.earaircraft.com/lit.php3
About the basics of ANR techniques I would suggest to read this:
http://www.anrheadsets.com/tutorial101-1.asp
Hopefully these helped even a bit.