What you described will not work. You cannot have 2 batteries simultaneously in series (for the ac) and in parallel (for the aircraft).
I have an all electric ac in the -10 that has the same setup that you described.
As posetd by someone above..if you center tap an additional "12 volt" load from the battery array you will have one battery with a higher amp draw than the other and over time you will see one battery voltage drop lower and lower while the the alternator continues to produce 28 volts. this means the other battery will be seeing higher and higher voltage. 15-16-17 volts as the other battery is 13-12-11 volts.
To remidy the problem there are several options.
The most desirable options for our application is:
1) Get a 24-12 volt converter with a high enough amp rating to handle the 12 volt load.
In the old days this was relatively inefficent and weighed a lot -10-15 lb for something that would handle 10-20 amp.
Nowdays you can get a switching power supply that is very efficent (92-98%) and is fairly light (cant remember but 3 lb should get you 20 amps or close to it.
2) get a battery equalizer. This is basicaly a 24-12 volt converter except instead of outputing a steady 13.8 volt regardless of input. It will output 50% of the input voltage. This is then used to charge the second battery (maintain an equal charge) the benifits of the equaizer are you can have an intermitant 12 volt load (fuel pump, landing light, flaps, trim, etc.) that exceeds the amp rating of the converter and then when the intermitent load is removed the equalizer will exchange charge from one battery to the other.
I have the equalizer set-up and have had no problems whatsoever.
This is what I used. You only need a big enough converter to recover the charge imbalance during normal cruise.
If you decide to go with a 24-12 volt converter I have a new in box Redarc CE20-13.8 which is a 20 amp converter that I would sell.