One other data point to think about concerning your thoughts on buying just what you need and no more. As Mike said, you will find plenty of uses for it after the tanks. It does last a long time if you do keep it in the freezer. The colder the better. Also, I can tell you from my experience, one thing I can add is that if you think you have used enough on a rivet, fillet, corner, whatever; well, give it some more.
Many builders, ok stating this as a guilty party, think they can use minimal amounts in order to save weight. Building light is an admirable goal but one must know the times to shave some weight and times not to do so. Applying tank sealant is NOT one of those times. Use the sealant liberally on your tank. Speaking from multiple years of chasing leaks in my tanks I can say if you do this you will have little chance of leaks later on.