Always learning
It is precisely these instances where I break out the FAR/AIM (get one if you don't have one). It is always better to find it yourself so you can be SURE it is accurate, and I prefer a paper vs PDF copy, you will always pick up something you forgot or didn't know (did you know you can fly VFR above 18,000 ft and no its not a trick question about >60,000). These are from memory, so I might be off a bit.
MVA=Minimum Vectoring Altitude
Minimum altitude (with certain exception like approaches) that ATC can vector you. It is based upon radar reception/resolution. They are altitudes in sectors around the radar station and are NOT based upon clearance from obstacles I think...just radar, the controller has other info to keep you clear of obstacles.
MRA=Minimum Reception Altitude. Lowest altitude on a published route segment where reception (of the defining NAVAID mind you) is assured.
MOCA=Min Obstacle Clearance Altitude. Lowest altitude on the route segment that assures obstacle clearance for the entire route. In the US this ALSO assures acceptable (note the difference from MRA) NAVAID reception to 22 mi from the station. This is like the altimeter...it can be a liar. The obstacle height, plus 1000ft/2000 (mountainous) is where they get this number, but the obstacle height is rounded to the nearest 100 ft, so 49 is the same as 0. I have notices in a lot of the areas where I fly lower than the towers (pensacola) there are a lot of towers listed in the high 40's (1049, 2048, etc).
MEA=Min Enroute Altitude. This is basically a combination...and what you want to fly. It provides obstruction clearance, reception of NAVAID, and also adequate comms, but I am not sure that one is guaranteed. This is a good starting point for planning purposes, then round up to the next highest standard cruising altitudes. Use that as your MINIMUM. Even if flying VFR, why not give yourself the best shot if you need any of the aforementioned services.
Finally, grab a sectional (just for the legend) and look them up in this pic. I like using these intersections (in the gulf-side bend area of FLorida) because since we have no mountains, it is a good combination of a lot of these important altitudes. Particularly look at HEVVN