I'm sure you could do anything you want, but why would you want to go to all that extra effort? Why not just sell the -6 kit and buy a -8?
You'd have to redesign the interior, seats, controls, re-analyze the structure, redesign the canopy, and when it's all done you'd probably have a huge CG issue since the -6 wasn't designed to have someone sitting in what would essentially be the baggage area. While you're at it, check out the width/length specs for the cockpit on Van's site because they're not real close.
RV-6 = 43" wide RV-8 = 33" wide (both measurements at the widest point)
RV-6 = 47" long RV-8 = 81" long
Personally I think you'd have a hard time making it work.
PJ
40032