No, Really! Why would you want to???
The only reason (that I could think of) for a lurker to ask this question, is that he may think that it's simpler to pull pop rivets than it is to buck rivets. If someone thought that they were going to spend a lot of time with little or no help, they may think that they couldn't shoot rivets by themselves.
If that's the reason for this question, then the real question should be "Can I shoot and buck rivets without assistance?"
The answer (for about 95% of the rivets on an RV) is YES! Very few of us had an assistant standing by with a bucking bar, just waiting for us to match-drill, deburr, countersink, and then buck a rivet. Most of us simply prepared the area, loaded the rivets in the prepared holes, picked up a 3X rivet gun in one hand and an bucking bar in the other, and pounded rivets. After bucking a handful of rivets, you'll get pretty good at bucking/shooting your own rivets. Much easier than pulling pop rivets, and more pleasing to the eye!
There are a few areas where assistance is required. For example, when you're closing out the wing skins, you're going to need help. Also, when you're closing out the skins on the fuselage. By the time you get to that stage of the construction, you'll probably have met a few RVers who would be happy to stop by, buck a couple of rivets, and drink your beer.