Titanium
You could make the RV-4, RV-6, RV-7 gear legs out of Titanium, but they would be expensive. I believe the Harmon Rockets / F-1 use titanium gear legs and are like the RV tube-N-socket gear. You would save weight, have higher strength, stiffness could be less (larger deflections, some steels are stiffer) and weight about 40% less by volume. I am all for saving weight and any RV can be built light with steel gear legs.
Not sure how many pounds you would save, 5 lbs, 10 lbs? Not sure it would be worth it. Many RV's come in way over what Van specs anyway, way over 10 lbs. Whlile other RV's come in at the low end of Vans weight spec. There are plenty of ways to keep 10lbs off and keep the weight down, but most builders tend to not watch the details that add up.
The weight difference between an O-320/O-360 is about 30lbs, the same as the difference between an O-360/IO-360(200hp). Wood or composite props are lighter than aluminum ones by 10-25lbs. Paint jobs can weigh 10lbs or they can weigh 30lbs. Did you prime every part inside and out. It all adds weight. The point is every one of the above items is a bigger saving than changing material of gear.
There are easier and cheaper ways to keep the empty weight down other than exotic metals for the gear. If you are going to add ever panel doo-dad, fancy interior and paint and a B747 inst panel with dual alternators/batteries, don't worry about weight, its going to be fat and 10 lbs will not help. Keep it light and build it per plans (except where the plans are wrong)
Cheers George