Bob is quite correct. Ordinary high-temperature RTV's are too often used for inappropriate applications.
A few words about 3M FireBarrier 2000+. It is also a silicone base sealant, specifically a special polysiloxane mixed with calcium carbonate, about 50-50 by weight. It will not itself burn or support combustion. However, when a thin layer is subjected to direct 2000F flame the silicone binder will burn away, leaving the calcium carbonate as a powder.
These properties do not make it a poor firewall sealant. The trick is how you use it. It is intended to fill gaps
in between components. When tucked into a gap or corner or placed under a mechanical shield (like a standard firewall shield) the sealant remains unaffected. If placed in direct contact with flame it should have a minimum thickness of about 1/4", in which case the silicone binder will cook out of the exposed surface, yet the calcium carbonate will remain to protect deeper layers of sealant.
Bottom line? You can't run a cable through a rubber grommet, smear some FireBarrier 2000 on it, and call it protected. It still needs a standard two-part stainless steel firewall shield over the assembly. The FB 2000 just makes it airtight.
The stuff should be terrific inside a tubular firewall penetration like the ones Rick described.
FireBarrier 2000+ appears to be safe on the cabin side of a hot firewall, "safe" meaning it doesn't seem to generate serious smoke and it doesn't burst into flame. However, be aware it may lose its adhesive ability, another good reason to use it with mechanical fixation...ie between things.
