Gary, I've seen two oil coolers installed on an RV-6 down here in Southeast Texas. It was a slightly tweaked IO-360 parallel valve engine developing more than 200 hp, and if I remember correctly, they were originally having trouble keeping the oil temps down during summertime climbs. The original configuration had the main cooler installed on the firewall with SCAT tubing feeding it off the back of the plenum.
The new & improved version had a small oil cooler between the inlet and the #2 cylinder that was plumbed in series. I'm going by memory, which is dangerous for me

, but I believe that's the way it was done. But it did solve their high temp problem.
Now, I don't want to second guess your problem, but I used to work in Ontario years ago and I don't remember it getting very hot during the summer. Is it possible that there is something else going on that's causing the higher temps? Maybe some sort of air path restriction? Without knowing how your system is configured (i.e. cooler location, size, type, plenum, etc.), it's tough to really say.
So yes, it is possible to install a secondary cooler and others have done it --but I'd be looking for a reason why your one cooler isn't doing the trick.