It's obviously not 'best'. Your task is to decide when you can apply the principle of 'better is the enemy of good enough'.
I used welding cable for battery, starter, and alternator wiring, and for the primary runs into the cockpit from the contactor(s). Various sizes as appropriate. Tradeoffs are much better flexibility (and lower cost, but that's not a significant factor) but thicker insulation with the welding cable. Additional advantage is that if you run out, a trip to the local welding supply's aviation department gets you moving again.
Many thousands of factory built a/c were wired with similar temperature-rated insulation (and much worse stuff), before the higher tech PTFE & related insulations came along. Very few went down in flames due to the temperature rating of the wire insulation.
Now, you get to decide. :-)
Charlie
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