You won’t, and testing will be difficult because best glide speed will change depending on flap deployment.
Your min rate of descent and max glide distances will be with flaps up
Remember TANSTAFL
There Ain’t No Such Thing As a Free Lunch.
Meaning that flaps do increase lift, but also increase drag, and very quickly the drag production exceeds the lift production.
Your method of matching flaps with aileron deflection is a good one, it’s a time tried method used by Bush Pilots for a very long time, it’s based on the theory that the manufacturer knew what they were doing and set aileron angle to where the aileron produces the most lift, before drag goes too high.
Many aircraft have three “notches” of flap, first notch produces lift with not much drag, second produces more lift, and much more drag, full flaps primarily produces drag, not much more lift than second notch but lots more drag.
Now on an aircraft that has excess thrust, min ground run can often be achieved with full flaps, this is because with enough thrust that large amount of drag can be overcome, if it’s light and has lots of power, I’d suspect an RV may fall into that category.
Pretty decent article explaining
https://www.experimentalaircraft.info/flight-planning/aircraft-best-glide-speed.php
Oh, and by the way, your method of marking flap degrees is exactly how they are marked on a Thrush Crop Duster, we had to put a light out there to illuminate the marking at night though.