Good plan John.
1: As far as I know gas tank caps are sold with viton seals by Vans and have been for about a decade now. Drain valve o rings must be replaced, I bought a pack of 20 from McMaster I'll send you a couple for free.
2:AFP injection is definitely compatible and so is AFP's electric fuel pump.
You can call Don Rivera and ask, while you have him on the phone tell him about your plans to use ethanol gas and you will be pleased with what he has to say.
3: Mechanical fuel pump. It's the wild card in the fuel system. No one is going to tell you that it is ethanol compatible but they have worked for the Vanguard Squadron for more than a decade in some cases burning almost pure ethanol.
4: Letting your plane sit around for too long is not a good idea no matter what kind of gas you have in it. Worst of all, it's not good for the pilot.
5: 100LL in one tank and 91 mogas in the other will take care of that
if you are worried about letting the mechanical pump sit around in mogas.
If you plan on using mogas just for cruise, you are good to go.
Want to go a step further and prevent vapor lock in your fuel system?
I like my system with a constant flow return line or FrankH system with 2 electric fuel pumps. Whichever way you go you can test the limits using mogas. For example take the plane out on a 100 degree day, let the engine heat up and taxi around on mogas. You'll find the limits for your fuel system
and if and when vapor lock occurs.
My installation can tolerate OAT 103F degrees 200 F oil temp and a hot engine using 91 E10 mogas without any hint of vapor lock or detonation.
(It's as far as I tested, I am sure it will tolerate even more heat.)
Like you, I generally take off and land on 100 LL just because I have it in the left tank but I am perfectly comfortable using mogas in all regimens of flight.